A supramolecular Tröger's base derived coordination zinc polymer for fluorescent sensing of phenolic-nitroaromatic explosives in water† †Electronic supplementary information (ESI) available: Spectroscopic (multinuclear NMR, IR HRMS) characterizations, optimized structure, TGA, powder diffraction and fluorescence titration profiles. See DOI: 10.1039/c6sc04367d Click here for additional data file.

A supramolecular Tröger's base derived coordination zinc polymer for fluorescent sensing of phenolic-nitroaromatic explosives in water.

A V-Shaped 4-amino-1,8-napthalimide derived tetracarboxylic acid linker (L; bis-[N-(1,3-benzenedicarboxylic acid)]-9,18-methano-1,8-naphthalimide-[b,f][1,5]diazocine) comprising the Tröger's base (TB) structural motif was rationally designed and synthesised to access a nitrogen-rich fluorescent supramolecular coordination polymer. By adopting the straight forward precipitation method, a new lum...

Reversible quantitative guest sensing via spin crossover of an iron(ii) triazole† †Electronic supplementary information (ESI) available: Synthetic details, NMR spectra, instrumentation, plus additional structural, magnetic and TGA information and diagrams. CCDC 1434103 and 1434104. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc04583e Click here for additional data file. Click here for additional data file.

Catalysis of “outer-phase” oxygen atom exchange reactions by encapsulated “inner-phase” water in {V15Sb6}-type polyoxovanadates† †Electronic supplementary information (ESI) available: IR spectra, thermogravimetric analysis data, powder diffraction patterns, crystal morphology data, details of solubility studies, additional crystallographic and magnetochemical data and comment on the unassigned signals in the ESI mass spectra. CCDC 1432847–1432850. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c5sc04571a Click here for additional data file. Click here for additional data file.

Light driven mesoscale assembly of a coordination polymeric gelator into flowers and stars with distinct properties† †Electronic supplementary information (ESI) available: Text, figures, and tables depicting different synthetic procedures, detailed experimental procedures, characterisation data including FT-IR, microscopic analyses, TGA, EDAX and SAED analyses, pore size distribution. See DOI: 10.1039/c5sc02233a Click here for additional data file.

Exceptional time response, stability and selectivity in doubly-activated phenyl selenium-based glutathione-selective platform† †Electronic supplementary information (ESI) available: 1H, 13C, 77Se and 2D NMR, HRMS spectra of compounds, details of the synthetic procedure, additional fluorescent spectra, confocal microscopy image, DFT calculation data, live imaging movie. See DOI: 10.1039/c5sc02090e Click here for additional data file. Click here for additional data file.